I'm curious about this, too, as I thought I read here that it was coming.
I'd actually never seen Dangerous Assignment until I recently caught episodes on antenna channel VPOD 59.3 at 10/9C. I'm not a huge Brian Donlevy fan, and was surprised by how much I liked the show.
The picture quality on VPOD seemed pretty good. I say "seemed" because now that I've discovered it and gotten used to watching it every night, they changed the schedule and are instead showing horrible quality prints of the Barbara Britton/Richard Denning series Mr. & Mrs. North. Oh well, at least I saw enough episodes to know that I'd buy the Dangerous Assignment series DVD if it ever materialized.