Seeing as how classic tv is never far from my mind, I too thought this was about 'Mr. Lucky'. Was just getting set to pull out my old Henry Mancini soundtrack album.
I can't answer if "Lucky" might ever show up on DVD, but a few years back I had an Emmy FYC DVD that contained four episodes. I can't remember what they all were, but I remember the pilot was included, along with an episode featuring Thomas Haden Church and an episode that revolved around a butcher.
You might want to try eBay or those types of sites to see if you can pick one up. I'd sell you mine, but I give it away a few years ago.