Alright, I've been circling this thread a while. I still would like to seeSyriana, Good Night and Good Luck, and Capote (and the list goes on), but I have a big enough sampling to make my picks. I can always modify it a little later. But I think the top few are pretty safe.
1.
The New World Review
2.
Kingdom of Heaven: Director's Cut Review
3.
King Kong Review
4.
Batman Begins Review
5.
The Constant Gardener Review
6.
Brokeback Mountain Review
7.
Munich Review
8.
A History of Violence Review
9.
Star Wars: Revenge of the Sith Review
10.
Sin City Review
Walk the Line got the boot.
3-5 were a bit of a bitch to rank (for lack of a better word). I can flip those around and around and be fairly satisfied. While I think The Constant Gardener is a better film than BB or KK, I "liked" those films more, and subsequently put them higher. Batman Begins was the biggest surprise for me, in terms of quality and emotional resonance. And BBM can occasionally creep into that mix when I think about it. My top four all surprised me, in some form or another. Each were better than I suspected they would (or could) be. Of these films, King Kong had the most flaws, but made up for it rather easily with Kong himself (and Naomi). My number #1 would have been my #1 in most years.
I overpraised some films upon initial viewing, and underpraised others. I get caught up in the excitement of films, and sometimes introspection makes them more or less than I originally thought. But this was a good year, and I like my list.
EDIT: Film I most wanted to see in theaters, but failed to do so, is
Kiss Kiss Bang Bang. I'll be blind buying it day of release. There is probably a great top ten list of films I *didn't* see, but I did what I could.
EDIT 2: Added KoH. My list is genre heavy...but I like genre, and I like it when genre films are well-crafted and meaningful.
None of my review links work (except KoH)

I'll fix that next week.