I know it is a bit obscure but I loved it and it seems to me she is getting a major push right now. Her character has returned to Marvel comics and will be getting a new comic book series soon. Spider-Woman will also be getting two US stamps:
http://www.comicbookresources.com/ne...em.cgi?id=8740
Spider-woman was chosen for this honor over Daredevil (cameo on one of Elektra's), Dr. Strange, Thor, Luke Cage and Ghost Rider, over more high profle heroes.
Since she is in the middle of a resurgence, I think the time is ripe for this to make it to DVD. It is just 16 episodes long.
Who owns the rights to it? It was a DePatie-Freleng Enterprises effort. Does Marvel have control of this or is it controlled by Disney?