Oh dear...I do not remember. I know the first DVD that I bought was "North By Northwest"....but TV DVD set??????? Best guess...Star Trek TOS Season One or TAGS Season One.
Monty Python's Flying Circus. Also the first time I bought something from an individual seller on the net. I think it was a sale place set up by yahoo. $125. I was worried I was going to get took. But they sent it out and it looked brand new. Was very surprised since it was selling for $170 or so on amazon at the time.
I wanted to watch some classic tv so badly. I finally gave up on TV Land. I bought seasons of Adam-12 & Hawaii Five-O. I'd hardly ever watched Adam-12 before but was quickly hooked.